Dichloromethane → Oleyl methane sulfonate

HRID 1499371노트

반응식

HRID 1499371 반응식
[CH2:1]([OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(Cl)Cl.[CH3:23][S:24](Cl)(=[O:26])=[O:25]>C(N(CC)CC)C>[CH3:23][S:24]([O:19][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:26])=[O:25]

참가 물질

5

반응물 3

HCID 6344DichloromethaneHCID 31297Methanesulfonyl chlorideHCID 5284499Oleyl Alcohol

생성물 1

HCID 6016198Oleyl methane sulfonate수율 96.4%

시약·촉매·용매 1

HCID 8471Triethylamine용매

실험 절차

Preparation A was repeated using 410 g oleyl alcohol, 2 liters DCM, 322 ml triethylamine, 194 g methane sulphonylchloride to yield 510 g (96%) oleyl methanesulphonate product.

후처리

  1. customPreparation

출처 및 근거

ORD 기록
ord-907c8480eb2f41e5826a86c35aba8efe
출처 데이터셋
uspto-grants-2015_12
특허 번호
US09200229B2

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