Dimethylformamide → HCID 74949036, 화합물

HRID 1513543노트

반응식

HRID 1513543 반응식
[C:1]([OH:12])(=O)[CH:2]=[CH:3][CH2:4][CH2:5][CH:6]=[CH:7][CH:8]=[CH:9][CH3:10].CN(C=O)C.S(Cl)([Cl:20])=O>C1(C)C=CC=CC=1>[C:1]([Cl:20])(=[O:12])[CH:2]=[CH:3][CH2:4][CH2:5][CH:6]=[CH:7][CH:8]=[CH:9][CH3:10]

참가 물질

5

반응물 3

HCID 6228DimethylformamideHCID 24386Thionyl ChlorideHCID 783839312,6,8-Decatrienoic acid

생성물 1

HCID 74949036HCID 74949036, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매2회

반응 조건

온도
5 °C

실험 절차

In an atmosphere of nitrogen, a toluene solution of the above-mentioned 2,6,8-decatrienoic acid (7) and DMF (3.7 g, 0.05 mol) were added to a 100 ml capacity flask, followed by cooling to 5° C. Thionyl chloride (11.9 g, 0.10 mol) was added dropwise to this, followed by stirring at 5° C. for 0.5 hour to obtain a toluene solution of 2,6,8-decatrienoic acid chloride (8).

출처 및 근거

ORD 기록
ord-13750b2ac8ae47199d50fe5ee39b40ce
출처 데이터셋
uspto-grants-2012_07
특허 번호
US08217192B2

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