Dimethylformamide → HCID 74949036, 화합물

HRID 1513548노트

반응식

HRID 1513548 반응식
C1(C)C=CC=CC=1.[C:8]([OH:19])(=O)[CH:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH:15]=[CH:16][CH3:17].CN(C=O)C.S(Cl)([Cl:27])=O>C1(C)C=CC=CC=1>[C:8]([Cl:27])(=[O:19])[CH:9]=[CH:10][CH2:11][CH2:12][CH:13]=[CH:14][CH:15]=[CH:16][CH3:17]

참가 물질

5

반응물 3

HCID 6228DimethylformamideHCID 24386Thionyl ChlorideHCID 86653159HCID 86653159, 화합물

생성물 1

HCID 74949036HCID 74949036, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매

반응 조건

온도
5 °C

실험 절차

In an atmosphere of nitrogen, the 2,6,8-decatrienic acid toluene solution obtained in the above and DMF (3.7 g, 0.05 mol) were added to a 100 ml capacity flask, followed by cooling to 5° C. Thionyl chloride (11.9 g, 0.10 mol) was added dropwise to this and stirring was carried out at 5° C. for 0.5 hour to obtain a toluene solution of 2,6,8-decatrienoic acid chloride.

후처리

  1. additionwere added to a 100 ml capacity flask

출처 및 근거

ORD 기록
ord-f8baae808ba9401d91ae0cd6a04dd613
출처 데이터셋
uspto-grants-2012_07
특허 번호
US08217192B2

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