참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Epichlorohydrin | HCID 7835 | — |
| 반응물 | 5-Phenyl-2,4-pentadienoic acid | HCID 73777 | — |
| 촉매 | Tetraethylammonium Bromide | HCID 6285 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | (Oxiran-2-yl)methyl 5-phenylpenta-2,4-dienoate | HCID 53778512 | — |
반응 단계
To 9.0 g of cinnamylideneacetic acid (manufactured by Lancaster) were added 3.5 g of tetraethylammonium bromide (manufactured by Wako Pure Chemical) and 100 ml of epichlorohydrin (manufactured by Wako Pure Chemical), the mixture was heated to reflux at 110° C. for 3 hours, 50 ml of distilled water was added thereto and an organic layer was separated and concentrated in vacuo at 80° C. to give 17.3 g of glycidyl cinnamylideneacetate. An epoxy equivalent of this glycidyl cinnamylideneacetate was 444.3.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US08222399B2 |
|---|
| 출처 데이터셋 | uspto-grants-2012_07 |
|---|
| ORD ID | ord-51d1f2b4d39944b99cd59368ea238e8e |
|---|
| 출처 메모 | uspto-grants-2012_07 |
|---|
