Methanol → Methyl 4-[(2-methoxyethyl)sulfanyl]benzoate

반응식

[CH3:1][O:2][CH2:3][CH2:4][S:5][C:6]1[CH:14]=[CH:13][C:9]([C:10]([OH:12])=[O:11])=[CH:8][CH:7]=1.S(=O)(=O)(O)O.[CH3:20]O>>[CH3:20][O:11][C:10](=[O:12])[C:9]1[CH:13]=[CH:14][C:6]([S:5][CH2:4][CH2:3][O:2][CH3:1])=[CH:7][CH:8]=1

참가 물질

반응물 3

HCID 887Methanol

HCID 1118Sulfuric Acid

HCID 20119783HCID 20119783, 화합물

생성물 1

HCID 58022768Methyl 4-[(2-methoxyethyl)sulfanyl]benzoate수율 78%

실험 절차

4-(2-Methoxy-ethylsulfanyl)-benzoic acid was esterified in methanol by adding catalytic amount of sulfuric acid. Subsequent work up afforded 4 g of desired product in 78% yield.

출처 및 근거

ORD 기록: ord-9fd5dde44a244d938276201ec2b6fe92
출처 데이터셋: uspto-grants-2012_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08227492B2

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