2-Cyclopenten-1-one → 6,6-Diethoxybicyclo[3.2.0]heptan-2-one
반응식
[C:1]1(=[O:6])[CH2:5][CH2:4][CH:3]=[CH:2]1.[CH2:7]([O:9][C:10]([O:12][CH2:13][CH3:14])=[CH2:11])[CH3:8]>CCCCC>[CH2:7]([O:9][C:10]1([O:12][CH2:13][CH3:14])[CH2:11][CH:5]2[CH:4]1[CH2:3][CH2:2][C:1]2=[O:6])[CH3:8]참가 물질
4
실험 절차
To a solution of cyclopent-2-enone (3.7 g, 45 mmol) in pentane (80 mL) was added 1,1-diethoxyethene (89 mL, 677 mmol). The mixture was put in an ACE Photo Reactor (450 W lamp), and stirred at RT for 20 hr. It was concentrated to give the title compound as a pale yellow oil.
후처리
- concentrationIt was concentrated
출처 및 근거
- ORD 기록
- ord-a18f7a9aad3a4c5c930b74ff4045358d
- 출처 데이터셋
- uspto-grants-2010_06
- 특허 번호
- US07732480B2
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