5-Chloro-1-propylindoline-2,3-dione → 5-Chloro-2-oxo-1-propylindolin-3-yl benzoate

반응식

[C:1]([O:9][CH:10]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[N:12]([CH2:19][CH2:20][CH3:21])[C:11]1=[O:22])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:23]C1C=C2C(=CC=1)N(CCC)C(=O)C2=O>>[C:1]([O:9][CH:10]1[C:18]2[C:13](=[CH:14][CH:15]=[C:16]([Cl:23])[CH:17]=2)[N:12]([CH2:19][CH2:20][CH3:21])[C:11]1=[O:22])(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

반응물 2

HCID 29882815-Chloro-1-propylindoline-2,3-dione

HCID 904164392-Oxo-1-propylindolin-3-yl benzoate

생성물 1

HCID 904179755-Chloro-2-oxo-1-propylindolin-3-yl benzoate

실험 절차

Was prepared in a method analogous to 2-oxo-1-propylindolin-3-yl benzoate using 5-chloro-1-propylindoline-2,3-dione. 1H-NMR δ 8.11 (dd, 2H), 7.60 (dt, 1H), 7.47 (m, 3H), 7.35 (dd, 1H), 6.83 (d, 1H), 6.13 (s, 1H), 3.73 (m, 2H), 1.77 (m, 2H), 1.04 (t, 3H).

출처 및 근거

ORD 기록: ord-ac245cbc20db4e2eb920cce7b0da11d2
출처 데이터셋: uspto-grants-2015_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09079853B2

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