Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl mercaptan → (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl mercaptan | HCID 7509 | — |
| 반응물 | Methyl (2S)-2-oxiranecarboxylate | HCID 10942355 | — |
| 생성물 | (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester | HCID 59639322 | 92% |
반응 단계
This reaction was performed as previously described by Deechongkit, S.; You, S.-L.; Kelly, J. W. Org. Lett. 2004, 6, 497, using (S)-Methylglycidate 110a and Benzyl mercaptan. (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester 110b (7.41 g, 31.41 mmol, 92%) was isolated as a viscous oil: MS calcd. for C11H14O3S (M+H+) 227.1, found 227.3.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07732449B2 |
| 출처 데이터셋 | uspto-grants-2010_06 |
| ORD ID | ord-27bc3950df9e4290b5641d3488fcb1c7 |
| 출처 메모 | uspto-grants-2010_06 |