3,5-Dinitrosalicylaldehyde → HCID 178449924, 화합물

반응식

[N+:1]([C:4]1[C:5]([OH:15])=[C:6]([CH:9]=[C:10]([N+:12]([O-:14])=[O:13])[CH:11]=1)[CH:7]=O)([O-:3])=[O:2].[C:16]([NH:20][OH:21])([CH3:19])([CH3:18])[CH3:17]>>[N+:1]([C:4]1[C:5]([OH:15])=[C:6]([CH:7]=[N+:20]([C:16]([CH3:19])([CH3:18])[CH3:17])[O-:21])[CH:9]=[C:10]([N+:12]([O-:14])=[O:13])[CH:11]=1)([O-:3])=[O:2]

참가 물질

반응물 2

HCID 755713,5-Dinitrosalicylaldehyde

HCID 98586N-tert-butylhydroxylamine

생성물 1

HCID 178449924HCID 178449924, 화합물

실험 절차

The title compound was prepared according to the procedure described in Example 13 using 3,5-dinitro-2-hydroxybenzaldehyde and N-tert-butylhydroxylamine. The title compound was isolated in 4.4% yield as a yellow crystalline solid, m.p. 200.3° C. (Rf=0.15 on a silica gel plate using 10:1 EtOAc/MeOH as an eluant).

후처리

customThe title compound was prepared

출처 및 근거

ORD 기록: ord-fb98f1652e0e4a8ba384991afd8e2338
출처 데이터셋: uspto-grants-2001_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06197826B1

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