Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydroxylamine → 6-Nitroquinoxalin-5-amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydroxylamine | HCID 787 | — |
| 반응물 | Quinoxaline, 6-nitro- | HCID 96029 | — |
| 반응물 | Sodium borohydride | HCID 4311764 | — |
| 생성물 | 6-Nitroquinoxalin-5-amine | HCID 13177513 | — |
| 생성물 | 1,2,3,4-Tetrahydro-5-amino-6-nitroquinoxaline | HCID 14617819 | — |
반응 단계
5-Amino-6-nitroquinoxaline was synthesized by reaction of 6-nitroquinoxaline with hydroxylamine in an alkaline medium in accordance with J. Chem. Soc., Perkin I, 1975, 1229. The product was reacted With sodium borohydride as in Example 1). The 1,2,3,4-tetrahydro-5-amino-6-nitroquinoxaline obtained in the form of brown crystals in a yield of 11.5% of the theoretical had a melting point of 213° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05089025 |
| 출처 데이터셋 | uspto-grants-1992_02 |
| ORD ID | ord-9551f644420a47b4b7e3823ee6f9c5ee |
| 출처 메모 | uspto-grants-1992_02 |