Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dichloromethane → Copper, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N(21)-,N(22)-,N(23)-,N(24)-]-
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | 5,10,15,20-Tetraphenyl-21,22-dihydroporphyrin | HCID 70186 | — |
| 반응물 | Cupric acetate monohydrate | HCID 165397 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | Copper, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N(21)-,N(22)-,N(23)-,N(24)-]- | HCID 135741320 | — |
반응 단계
Tetraphenylporphyrin (II) (16.80 g., 27.3 mmol) is dissolved in 2000 ml of chloroform under reflux. Copper (II) acetate monohydrate (5.45 g., 27.3 mmol) is dissolved in 600 ml of methanol, and added dropwise to the methylene chloride solution in about 15 minutes. After the addition is over, the solution is refluxed for 30 minutes and cooled. The completion of the reaction is checked by UV-VIS spectrophotometry. The product IIa is isolated by evaporation of the solvents.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05091502 |
| 출처 데이터셋 | uspto-grants-1992_02 |
| ORD ID | ord-e56dc25a2c0b4674950da31342da095e |
| 출처 메모 | uspto-grants-1992_02 |