Thionyl Chloride → 1,3,5-Trichloro-2-(2-chloroethoxy)benzene

HRID 1535042노트

반응식

HRID 1535042 반응식
[Cl:1][C:2]1[CH:11]=[C:10]([Cl:12])[CH:9]=[C:8]([Cl:13])[C:3]=1[O:4][CH2:5][CH2:6]O.S(Cl)([Cl:16])=O>[Cl-].C([N+](C)(C)C)C1C=CC=CC=1.C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:11]=[C:10]([Cl:12])[CH:9]=[C:8]([Cl:13])[C:3]=1[O:4][CH2:5][CH2:6][Cl:16]

참가 물질

5

반응물 2

HCID 24386Thionyl ChlorideHCID 963432-(2,4,6-Trichlorophenoxy)ethan-1-ol

생성물 1

HCID 112769591,3,5-Trichloro-2-(2-chloroethoxy)benzene

시약·촉매·용매 2

HCID 5963Benzyltrimethylammonium chloride촉매HCID 5943Carbon Tetrachloride용매

실험 절차

reacting the 2-(2,4,6-trichlorophenoxy)-ethanol with thionyl chloride in the presence of benzyl-trimethyl-ammonium chloride in a ratio of 1:60 by weight, at a temperature of from 50° C. to 80° C., in the presence of carbon tetrachloride as solvent to form 2-(2,4,6-trichlorophenoxy)-ethyl chloride.

출처 및 근거

ORD 기록
ord-64eae5a0b1284a73a659ced65478b9f5
출처 데이터셋
uspto-grants-1992_02
특허 번호
US05091578

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