반응식
C(=O)([O-])[O-].[Na+].[Na+].[CH3:7][C:8](C)(C1C=CC=C(C(C)(C)O)C=1)O.C(OC=C)(=O)C.[OH:27][C:28]([C:31]1[CH:36]=[CH:35][CH:34]=[C:33]([C:37]([CH3:42])([O:39][CH:40]=[CH2:41])[CH3:38])[CH:32]=1)([CH3:30])[CH3:29]>C1(C)C=CC=CC=1>[CH3:38][C:37]([C:33]1[CH:34]=[CH:35][CH:36]=[C:31]([C:28]([O:27][CH:7]=[CH2:8])([CH3:30])[CH3:29])[CH:32]=1)([O:39][CH:40]=[CH2:41])[CH3:42]참가 물질
6
반응 조건
- 온도
- 100 °C
실험 절차
To a mixture of di-μ-chlorobis(1,5-cyclooctadiene) diiridium(I) [Ir(cod)Cl]2 (67 mg, 0.1 mmol) and sodium carbonate (640 mg, 6 mmol) in toluene (5 ml) were added α,α,α′,α′-tetramethyl-1,3-benzenedimethanol (5 mmol) and vinyl acetate (2.15 g, 25 mmol), followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that 1-(1-hydroxy-1-methylethyl)-3-(1-methyl-1-vinyloxyethyl)benzene and 1,3-bis(1-methyl-1-vinyloxyethyl)benzene were formed in yields of 8% and 70%, respectively, with a conversion from α,α,α′,α′-tetramethyl-1,3-benzenedimethanol of 98%.
출처 및 근거
- ORD 기록
- ord-d6724aed35a6476fbc702863e8643653
- 출처 데이터셋
- uspto-grants-2010_06
- 특허 번호
- US07732645B2
연결된 노트
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