반응식
C(=O)([O-])[O-].[Na+].[Na+].OC1C=CC=CC=1C(C1C=CC=CC=1O)=O.C(OC=C)(=O)CC.[CH:30]([O:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][C:34]=1[C:39]([C:41]1[CH:46]=[CH:45][CH:44]=[CH:43][C:42]=1[O:47]C=C)=[O:40])=[CH2:31]>C1(C)C=CC=CC=1>[CH:30]([O:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][C:34]=1[C:39]([C:41]1[CH:46]=[CH:45][CH:44]=[CH:43][C:42]=1[OH:47])=[O:40])=[CH2:31]참가 물질
6
반응 조건
- 온도
- 100 °C
실험 절차
To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (3.81 g, 5.7 mmol) and sodium carbonate (24.9 g, 0.23 mol)) in toluene (280 ml) were added 2,2′-dihydroxybenzophenone (0.19 mmol) and vinyl propionate (0.75 mol), followed by stirring at 100° C. in an atmosphere of argon gas for 10 hours. The reaction mixture was analyzed by gas chromatography to find that bis(2-vinyloxyphenyl) ketone [i.e., bis(2-vinyloxyphenyl)methanone] and 2-hydroxyphenyl 2-vinyloxyphenyl ketone [i.e., 2-hydroxyphenyl(2-vinyloxyphenyl)methanone] were formed in yields of 82% and 5%, respectively, with a conversion from 2,2′-dihydroxybenzophenone of 99%.
출처 및 근거
- ORD 기록
- ord-2215ba69eddc4da69d446f5740d3620f
- 출처 데이터셋
- uspto-grants-2010_06
- 특허 번호
- US07732645B2
연결된 노트
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