Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Chloride → 4-Octen-3-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Chloride | HCID 5234 | — |
| 반응물 | 1-Chloro-3-methyl-2-butene | HCID 10429 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Decane | HCID 15600 | — |
| 촉매 | Dodecyltrimethylammonium chloride | HCID 8152 | — |
| 용매 | Acetone | HCID 180 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 4-Octen-3-one | HCID 84216 | 51% |
반응 단계
By using the same reaction vessel as used in Example 1, 10.45 g of prenyl chloride, 34.8 ml of acetone, 20.3 g of a 65 % aqueous caustic soda solution, 5 ml of n-decane and 0.264 g of lauryl trimethylammonium chloride were added into the vessel, and then the mixture was allowed to react for 12 hours at 30°C. with vigorous stirring. After the reaction was completed, 40 ml of water was added to the resultant solution to dissolve the sodium chloride. Methyl heptenone was produced as determined by using gas chromatography and the yield was 51 % calculated on the theoretical value.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03983175 |
| 출처 데이터셋 | uspto-grants-1976_09 |
| ORD ID | ord-a5927956efd9445caf5da00b502a3e76 |
| 출처 메모 | uspto-grants-1976_09 |