3-(4-Methoxyphenyl)-1-phenylprop-2-en-1-one → 8-(4-Methoxyphenyl)-10,10-dimethyl-6-phenyl-10H-pyrido[1,2-a]indolium perchlorate

HRID 1577039

반응식

HRID 1577039 반응식
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:6][C:7]1[C:15]([CH3:17])([CH3:16])[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[NH+:8]=1.[CH3:18][O:19][C:20]1[CH:25]=[CH:24][C:23]([CH:26]=[CH:27][C:28]([C:30]2[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=2)=O)=[CH:22][CH:21]=1>>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:18][O:19][C:20]1[CH:25]=[CH:24][C:23]([C:26]2[CH:27]=[C:28]([C:30]3[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=3)[N+:8]3[C:9]4[C:14]([C:15]([CH3:17])([CH3:16])[C:7]=3[CH:6]=2)=[CH:13][CH:12]=[CH:11][CH:10]=4)=[CH:22][CH:21]=1

참가 물질

3

반응물 2

HCID 941973-(4-Methoxyphenyl)-1-phenylprop-2-en-1-oneHCID 149131883H-Indole, 2,3,3-trimethyl-, perchlorate

생성물 1

HCID 123743708-(4-Methoxyphenyl)-10,10-dimethyl-6-phenyl-10H-pyrido[1,2-a]indolium perchlorate

실험 절차

2,3,3-Trimethyl-3H-indolium perchlorate (5 g.) and 3-(4-methoxyphenyl)-1-phenyl-prop-2-ene-1-one (10 g.) were heated together on a steam bath for three hours. The cooled mixture was purified by recrystallization from acetonitrile. The melting point is 258°C.

후처리

  1. customThe cooled mixture was purified by recrystallization from acetonitrile

출처 및 근거

ORD 기록
ord-a47521511e23444a9257f90a109acb4d
출처 데이터셋
uspto-grants-1976_09
특허 번호
US03983288

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