Dimethylamine → HCID 20570904, 화합물

HRID 1577500노트

반응식

HRID 1577500 반응식
C[O-].[Na+].[CH3:4][CH:5]([C:7]1[CH:11]=[CH:10][O:9][C:8]=1[C:12]([O:14]C)=O)[CH3:6].[CH3:16][NH:17][CH3:18]>CO>[CH3:16][N:17]([CH3:18])[C:12]([C:8]1[O:9][CH:10]=[CH:11][C:7]=1[CH:5]([CH3:6])[CH3:4])=[O:14]

참가 물질

5

반응물 3

HCID 674DimethylamineHCID 10942334Sodium MethoxideHCID 67355685HCID 67355685, 화합물

생성물 1

HCID 20570904HCID 20570904, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

A solution of sodium methoxide (3.3 g) and 3-(1-methylethyl)-2-furancarboxylic acid, methyl ester (14 g) in dry methanol (50 ml) was treated with dimethylamine gas during 2 hours. The solvent was removed in vacuo and the residue was dissolved in diethyl ether (150 ml) and washed with water (100 ml). The ethereal extract was dried over anhydrous sodium sulphate and evaporation of the solvent gave the title compound (12 g) as an oil.

후처리

  1. customThe solvent was removed in vacuo
  2. dissolutionthe residue was dissolved in diethyl ether (150 ml)
  3. washwashed with water (100 ml)
  4. extractionThe ethereal extract
  5. dry with materialwas dried over anhydrous sodium sulphate and evaporation of the solvent

출처 및 근거

ORD 기록
ord-48cb1121fc8d471d9d946acb7638b45d
출처 데이터셋
uspto-grants-1981_09
특허 번호
US04288443

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