3-Bromophenyl Isothiocyanate → N-(3-bromophenyl)-2-decyltetrahydro-2H-1,3-thiazine3-carbothioamide
반응식
[CH2:1]([CH:11]1[NH:16][CH2:15][CH2:14][CH2:13][S:12]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Br:17][C:18]1[CH:19]=[C:20]([N:24]=[C:25]=[S:26])[CH:21]=[CH:22][CH:23]=1>>[Br:17][C:18]1[CH:19]=[C:20]([NH:24][C:25]([N:16]2[CH2:15][CH2:14][CH2:13][S:12][CH:11]2[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])=[S:26])[CH:21]=[CH:22][CH:23]=1참가 물질
3
실험 절차
The procedure of Example 25 was repeated, except that the reactants consisted of 0.9 g. of 2-decyltetrahydro-2H-1,3-thiazine and 0.7 g. of 3-bromophenyl isothiocyanate. The product was recrystallized from ethanol to give N-(3-bromophenyl)-2-decyltetrahydro-2H-1,3-thiazine3-carbothioamide, m.p. 73°-4°. The following elemental microanalysis was obtained:
후처리
- customThe product was recrystallized from ethanol
출처 및 근거
- ORD 기록
- ord-31baf5a016914eddb43065a33786e0d9