4-Nitrobenzenesulfonyl chloride → 2-(3-Nitrophenyl)ethyl 4-nitrobenzenesulfonate

반응식

[CH3:1][S:2]([O:5][CH2:6][CH2:7][C:8]1[CH:13]=[CH:12][CH:11]=[C:10]([N+:14]([O-:16])=[O:15])[CH:9]=1)(=[O:4])=[O:3].[N+:17]([C:20]1[CH:21]=[C:22](CCO)C=[CH:24][CH:25]=1)([O-:19])=[O:18].[N+](C1C=CC(S(Cl)(=O)=O)=CC=1)([O-])=O>>[N+:17]([C:20]1[CH:21]=[CH:22][C:1]([S:2]([O:5][CH2:6][CH2:7][C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([N+:14]([O-:16])=[O:15])[CH:9]=2)(=[O:3])=[O:4])=[CH:24][CH:25]=1)([O-:19])=[O:18]

참가 물질

반응물 3

HCID 74044-Nitrobenzenesulfonyl chloride

HCID 1040583-Nitrophenylethyl alcohol

HCID 219738843-Nitrophenethyl methanesulfonate

생성물 1

HCID 574442742-(3-Nitrophenyl)ethyl 4-nitrobenzenesulfonate수율 68%

실험 절차

The title compound was prepared in 68% yield using a similar procedure to description D4 starting from 2-(3-nitro-phenyl)ethanol and 4-nitrobenzenesulfonyl chloride.

출처 및 근거

ORD 기록: ord-eef2bf9053ff4888bea3fdbe16ca0553
출처 데이터셋: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07732600B2

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