D-Glucose → Nitrous acid, hexyl ester

HRID 1579000

반응식

HRID 1579000 반응식
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[N:8]([O-:10])=[O:9].CN([S+](N(C)C)N(C)C)C.OC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O.[N+](CCCCCC)([O-])=O>C(#N)C>[N:8]([O:10][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[O:9]

참가 물질

6

반응물 4

HCID 5793D-GlucoseHCID 81011-BromohexaneHCID 125891-NitrohexaneHCID 21557485Tris(dimethylamino)sulfonium nitrite

생성물 1

HCID 6365123Nitrous acid, hexyl ester

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

A 165-mg (1 mmole) sample of 1-bromohexane was added to 0.5 ml (1 mmole) of 2M tris(dimethylamino)sulfonium nitrite in acetonitrile. The course of the reaction was followed by glc analysis. No further reaction occurred after 15 min. Glc analysis showed that 1-nitrohexane and 1-hexyl nitrite were formed in a 70:30 ratio.

후처리

  1. customNo further reaction

출처 및 근거

ORD 기록
ord-b299314bb2084a96854535dde897a5ae
출처 데이터셋
uspto-grants-1976_02
특허 번호
US03940402

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