Hydrogen Cyanide → HCID 23344788, 화합물

HRID 1579165노트

반응식

HRID 1579165 반응식
[C:1]([NH:5][N:6]=[C:7]([CH:9]1[CH2:11][CH2:10]1)[CH3:8])([CH3:4])([CH3:3])[CH3:2].[CH:12]#[N:13]>>[C:1]([NH:5][NH:6][C:7]([C:12]#[N:13])([CH:9]1[CH2:10][CH2:11]1)[CH3:8])([CH3:4])([CH3:2])[CH3:3]

참가 물질

3

반응물 2

HCID 768Hydrogen CyanideHCID 85772048HCID 85772048, 화합물

생성물 1

HCID 23344788HCID 23344788, 화합물

실험 절차

A solution of 8.7g methyl cyclopropyl ketone t-butylhydrazone in 20 ml liquid hydrocyanic acid was heated for 6 hours in a pressure bottle at 60°C. The solution was cooled, poured into ice water and the aqueous solution extracted twice with ether. The ether extracts were combined, washed with saturated sodium bicarbonate solution, dried over sodium sulfate, filtered and the ether evaporated off. The yield was 10.0g (99%) of a brown liquid. The infrared spectrum was consistent with the structure of the proposed product.

후처리

  1. temperatureThe solution was cooled
  2. extractionthe aqueous solution extracted twice with ether
  3. washwashed with saturated sodium bicarbonate solution
  4. dry with materialdried over sodium sulfate
  5. filtrationfiltered
  6. customthe ether evaporated off

출처 및 근거

ORD 기록
ord-260d94e5ef154812a94e6f760bba7180
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03931143

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