Bromine → HCID 21567566, 화합물

HRID 1579168노트

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HRID 1579168 반응식
[C:1]([NH:5][NH:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:15]#[N:16])[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

참가 물질

4

반응물 3

HCID 24408BromineHCID 21567553HCID 21567553, 화합물HCID 23344788HCID 23344788, 화합물

생성물 1

HCID 21567566HCID 21567566, 화합물

실험 절차

1-t-Butylazo-1-cyanocyclooctane was prepared in 93% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocyclooctane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 55°C.

후처리

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 55°C.

출처 및 근거

ORD 기록
ord-95b94a0eba6743728f8e1cf34313af2e
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03931143

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