Bromine → HCID 21567580, 화합물

HRID 1579170노트

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HRID 1579170 반응식
[C:1]([NH:5][NH:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:3])[CH3:2].BrBr.C(NNC(C#N)(C1CC1)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]1([C:14]#[N:15])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1)([CH3:4])([CH3:2])[CH3:3]

참가 물질

4

반응물 3

HCID 24408BromineHCID 21567558HCID 21567558, 화합물HCID 23344788HCID 23344788, 화합물

생성물 1

HCID 21567580HCID 21567580, 화합물

실험 절차

1-t-Butylazo-1-cyanocycloheptane was prepared in 100% crude yield by oxidizing 1-t-butylhydrazo-1-cyanocycloheptane with bromine using the same procedure described in Example XIIIC for the oxidation of 1-t-butylhydrazo-1-cyano-1-cyclopropylethane. The crude product was chromatographed over alumina and the product eluted with pentane. The infrared spectrum of the purified product was consistent with the structure of the desired azo. The compound has a 10 hour half-life in trichlorobenzene at approximately 68°C.

후처리

  1. customThe crude product was chromatographed over alumina
  2. washthe product eluted with pentane
  3. customat approximately 68°C.

출처 및 근거

ORD 기록
ord-452db6448fa142be9b0c1d9f0f65a949
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03931143

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