tert-Butyl hydroperoxide → 2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2,7-trioxide

HRID 1579947노트

반응식

HRID 1579947 반응식
[N:1]12[CH2:10][N:5]3[CH2:6][P:7]([CH2:9][N:3]([CH2:4]3)[S:2]1(=[O:12])=[O:11])[CH2:8]2.C([O:17]O)(C)(C)C>>[N:1]12[CH2:10][N:5]3[CH2:6][P:7](=[O:17])([CH2:9][N:3]([CH2:4]3)[S:2]1(=[O:12])=[O:11])[CH2:8]2

참가 물질

3

반응물 2

HCID 6410tert-Butyl hydroperoxideHCID 218292932-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-dioxide

생성물 1

HCID 218292942-Thia-1,3,5-triaza-7-phosphaadamantane 2,2,7-trioxide수율 93.3%

실험 절차

2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-dioxide (0.5g, 0.0024 mole) and t-butyl hydroperoxide (70% solution, 0.3 g, 0.0024 mole) were stirred in a 25 ml acetone-25 ethanol solution for 1 hour at room temperature. The solution was filtered to yield 0.5 g of crude 2-thia-1,3,5-triaza-7-phosphaadamantane 2,2,7-trioxide (92% yield) [MP 245°-6° (propanol)].

후처리

  1. filtrationThe solution was filtered

출처 및 근거

ORD 기록
ord-cfeb113a60a6464a88942d4add8c1073
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03932390

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