Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sulfuric Acid → Benzoic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sulfuric Acid | HCID 1118 | — |
| 반응물 | Ethanol, 2-methoxy-, calcium salt (2:1) | HCID 178496199 | — |
| 반응물 | HCID 178507079 | HCID 178507079 | — |
| 생성물 | Benzoic Acid | HCID 243 | 60% |
반응 단계
To the suspension was added 0.2 mole of di(2-methoxyethoxy)-calcium. On stirring the mixture, the phenyl-sodium reacted and went into solution. On carbonation, followed by treatment with dilute sulfuric acid, the mixture gave 14.6 grams of benzoic acid (a 60% yield, based on the amount of chlorobenzene used), illustrating that the sodium-containing, organometallic product had the same reactivity toward carbon dioxide as does phenyl-sodium.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03932545 |
| 출처 데이터셋 | uspto-grants-1976_01 |
| ORD ID | ord-ebb12c78fbfc4cc88a1ed962f4a19865 |
| 출처 메모 | uspto-grants-1976_01 |