Sodium Carbonate → 2-Ethylhexanoylmethylenetriphenylphosphorane

HRID 1581112노트

반응식

HRID 1581112 반응식
[Cl-].[O:2]=[C:3]([CH:24]([CH2:29][CH3:30])[CH2:25][CH2:26][CH2:27][CH3:28])[CH2:4][P+:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.C(=O)([O-])[O-].[Na+].[Na+]>O>[CH2:29]([CH:24]([CH2:25][CH2:26][CH2:27][CH3:28])[C:3]([CH:4]=[P:5]([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)=[O:2])[CH3:30]

참가 물질

4

반응물 2

HCID 10340Sodium CarbonateHCID 215614842-Oxo-3-ethylheptyltriphenylphosphonium chloride

생성물 1

HCID 215614912-Ethylhexanoylmethylenetriphenylphosphorane

시약·촉매·용매 1

HCID 962Water용매

실험 절차

Crude 2-oxo-3-ethylheptyltriphenylphosphonium chloride (88 g.) was added to a solution of sodium carbonate (100 g.) in water (1 litre) and the mixture stirred vigorously for 24 hours. The mixture was then extracted with diethyl ether and the extracts dried over magnesium sulphate. The solvent was evaporated and the crude product (63.3 g.) recrystallised from petrol (b.p. 60°-80°C.) to give 2-ethylhexanoylmethylenetriphenylphosphorane, m.p. 105.5°-107.5°C. (Found: C, 80.2; H, 7.5. C27H31OP requires C, 80.5; H, 7.5%).

후처리

  1. extractionThe mixture was then extracted with diethyl ether
  2. dry with materialthe extracts dried over magnesium sulphate
  3. customThe solvent was evaporated
  4. customthe crude product (63.3 g.) recrystallised from petrol (b.p. 60°-80°C.)

출처 및 근거

ORD 기록
ord-caecd330994142eb9376a3d1011e8b56
출처 데이터셋
uspto-grants-1976_01
특허 번호
US03935261

반응 노트

불러오는 중…