Naphthalene → Lithium Naphthalene

HRID 1586625노트

반응식

HRID 1586625 반응식
[Li:1].[CH:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1>>[Li:1].[CH:10]1[C:11]2[C:6](=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:7]=[CH:8][CH:9]=1

참가 물질

3

반응물 2

HCID 931NaphthaleneHCID 3028194Lithium

생성물 1

HCID 57466756Lithium Naphthalene

실험 절차

Lithium shot (1.7 grams) packed in mineral oil (Lithcoa Corporation) was magnetically stirred with naphthalene (15 grams) in dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon purged amber sure-seal bottle equipped with a rubber septum. The resultant dark green lithium naphthalide solution was 2 molar in concentration as determined by titration with 0.1 molar hydrochloric acid and by size exclusion chromatographic analysis of the polymeric products obtained after reaction with multiblock component monomers.

후처리

  1. dry with materialin dry freshly distilled tetrahydrofuran (50 milliliters) for 16 hours at 25° C. in an argon
  2. custompurged
  3. customamber sure-seal bottle
  4. customequipped with a rubber septum
  5. concentrationin concentration
  6. customobtained
  7. customafter reaction with multiblock component monomers

출처 및 근거

ORD 기록
ord-102b6d789f974737b7d17fe7c19a4db1
출처 데이터셋
uspto-grants-1993_06
특허 번호
US05215846

반응 노트

불러오는 중…