HCID 149351, 화합물 → HCID 54375391, 화합물
반응식
[N+:1]([C:4]1[CH:13]=[C:12]2[C:7]([C:8](=[CH:14][C:15]3[CH:20]=[CH:19][C:18]([N+:21]([O-])=O)=[CH:17][CH:16]=3)[O:9][C:10]2=[O:11])=[CH:6][CH:5]=1)([O-])=O.CCCCC[C@H](O)C=C[C@@H]1[C@@H](CCCCCCC(O)=O)C(=O)C[C@H]1O>[Fe]>[NH2:1][C:4]1[CH:13]=[C:12]2[C:7]([C:8](=[CH:14][C:15]3[CH:20]=[CH:19][C:18]([NH2:21])=[CH:17][CH:16]=3)[O:9][C:10]2=[O:11])=[CH:6][CH:5]=1참가 물질
4
실험 절차
6-Nitro-3-(p-nitrophenylmethylene)phthalide prepared by the process mentioned in "Nihon Kagaku Kaishi (Journal of Japan Chemical Society)", page 110 (1973) was reduced with iron powder by conventional method and the resulting crude product was crystallized from isopropanol to obtain 6-amino-3-(p-aminophenylmethylene)phthalide.