Zinc Acetate → ZINC 4-methylpicolinate

HRID 1587702

반응식

HRID 1587702 반응식
[CH3:1][C:2]1[CH:7]=[CH:6][N:5]=[C:4]([C:8]([OH:10])=[O:9])[CH:3]=1.C([O-])(=O)C.[Zn+2:15].C([O-])(=O)C>O>[CH3:1][C:2]1[CH:7]=[CH:6][N:5]=[C:4]([C:8]([O-:10])=[O:9])[CH:3]=1.[Zn+2:15].[CH3:1][C:2]1[CH:7]=[CH:6][N:5]=[C:4]([C:8]([O-:10])=[O:9])[CH:3]=1

참가 물질

4

반응물 2

HCID 11192Zinc AcetateHCID 27628204-Methylpyridine-2-carboxylic acid

생성물 1

HCID 67852794ZINC 4-methylpicolinate수율 82.3%

시약·촉매·용매 1

HCID 962Water용매2회

실험 절차

To a solution of 0.49 g (3.6 mmol) of 4-methylpicolinic acid dissolved in 2.5 ml of water, a solution of 0.40 g (1.8 mmol) of zinc acetate.dihydrate dissolved in 1.5 ml of water was dropwise added while stirring. After the dropwise addition, the mixture was stirred at room temperature for one hour. Because no solid was precipitated, the mixture was evaporated to dryness under a reduced pressure, and the solid obtained was washed with acetone under heating to give 0.50 g of the desired zinc salt. No recrystallization was possible from either water or ethanol (yield 79.1%).

후처리

  1. additionwas dropwise added
  2. additionAfter the dropwise addition
  3. stirringthe mixture was stirred at room temperature for one hour
  4. customBecause no solid was precipitated
  5. customthe mixture was evaporated to dryness under a reduced pressure
  6. customthe solid obtained
  7. washwas washed with acetone
  8. temperatureunder heating

출처 및 근거

ORD 기록
ord-5aa083d5bcf040dbb50bf296d63dd46c
출처 데이터셋
uspto-grants-1993_06
특허 번호
US05219847

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