Bromine → HCID 70456026, 화합물

HRID 1589298노트

반응식

HRID 1589298 반응식
[CH3:1][O:2][C:3]1[CH:8]=[C:7]([S:9][CH3:10])[CH:6]=[CH:5][C:4]=1[C:11]1[N:20]=[C:14]2[C:15](=[O:19])[NH:16][CH2:17][CH:18]=[C:13]2[N:12]=1.C([O-])(=[O:23])C.[Na+].BrBr>C(O)(=O)C>[CH3:1][O:2][C:3]1[CH:8]=[C:7]([S:9]([CH3:10])=[O:23])[CH:6]=[CH:5][C:4]=1[C:11]1[N:20]=[C:14]2[C:15](=[O:19])[NH:16][CH2:17][CH:18]=[C:13]2[N:12]=1

참가 물질

5

반응물 3

HCID 24408BromineHCID 517045Sodium AcetateHCID 70455630HCID 70455630, 화합물

생성물 1

HCID 70456026HCID 70456026, 화합물

시약·촉매·용매 1

HCID 176Acetic Acid용매2회

실험 절차

0.3 g of 2-(2-methoxy-4-methylmercapto-phenyl)-5H-imidazo[4,5-c]pyridin-4-one were suspended in 10 ml of 50% acetic acid, and 0.2 g of anhydrous sodium acetate were added thereto. 0.15 g of bromine, dissolved in 2 ml of glacial acetic acid, was added dropwise to the mixture, while stirring. After the reaction had ended the mixture was poured over ice, and the precipitate thus obtained was recrystallized from ethanol. Melting point: 267°-272° C. (decomposition).

후처리

  1. additionwas added dropwise to the mixture
  2. additionwas poured over ice
  3. customthe precipitate thus obtained
  4. customwas recrystallized from ethanol

출처 및 근거

ORD 기록
ord-fc11ee5874bc4708a1c6d4bce9ae20f3
출처 데이터셋
uspto-grants-1986_02
특허 번호
US04568680

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