1-Octadecene → HCID 178443003, 화합물

HRID 1589711

반응식

HRID 1589711 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[S:19][Cl:20]>>[CH3:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=[CH2:1].[S:19][Cl:20]

참가 물질

3

반응물 2

HCID 82171-OctadeceneHCID 15930840CID 15930840

생성물 1

HCID 178443003HCID 178443003, 화합물

실험 절차

Approximately 840 gm (3.0 mol. 90% purity) of octadecene was charged into a 2-liter reactor equipped with dropping funnel, reflux condenser, thermometer, and mechanical stirrer. Approximately 202.5 gm (1.5 mol.) of sulfur monochloride was added through the dropping funnel. Then the reaction mixture was heated to 95° to 100° C. to activate the sulfochlorination reaction. Moderate exotherm brought the temperature to 113° C. then the reaction was held at 110° C. for four hours. Near the end of the period at 110° C., the color became dark reddish. At completion, the product was left to cool slowly. This produced approximately 103 gm liquid material (C36H72S2Cl2).

후처리

  1. customequipped
  2. temperaturereflux condenser
  3. temperatureThen the reaction mixture was heated to 95° to 100° C.
  4. customthe sulfochlorination reaction
  5. customto 113° C.
  6. customat 110° C.
  7. waitAt completion, the product was left
  8. temperatureto cool slowly

출처 및 근거

ORD 기록
ord-4dbd8aba6979441681eddde33520ccf8
출처 데이터셋
uspto-grants-1993_04
특허 번호
US05199960

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