Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetate → HCID 54328202, 화합물

HRID 1596182노트

반응식

HRID 1596182 반응식
[CH2:1]([O:3][C:4](=[O:23])[CH:5]=[C:6]1[CH2:9][N:8](C(C2C=CC=CC=2)C2C=CC=CC=2)[CH2:7]1)[CH3:2].[H][H]>C(O)C.[OH-].[OH-].[Pd+2]>[CH2:1]([O:3][C:4](=[O:23])[CH2:5][CH:6]1[CH2:9][NH:8][CH2:7]1)[CH3:2]

참가 물질

5

반응물 2

HCID 53428664Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetateHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 54328202HCID 54328202, 화합물

시약·촉매·용매 2

HCID 9942167Palladium hydroxide촉매HCID 702Ethanol용매

실험 절차

To a solution of (1-benzhydrylazetidin-3-ylidene)-acetic acid ethyl ester (5.0 g, 16 mmol) in ethanol (200 mL) was added palladium hydroxide on carbon (1.5 g). This mixture was vigorously shaken under a 50 psi hydrogen atmosphere for 24 hrs, then filtered and concentrated to give an oil, used without additional purification.

후처리

  1. filtrationfiltered
  2. concentrationconcentrated
  3. customto give an oil
  4. customused without additional purification

출처 및 근거

ORD 기록
ord-0d8c71ddcce741c880b4bf11130e10cc
출처 데이터셋
uspto-grants-2001_09
특허 번호
US06291457B1

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