HCID 21190028, 화합물 → 4-Fluoro-2,6-dinitroaniline
반응식
[F:1][C:2]1[CH:7]=[C:6]([N+:8]([O-:10])=[O:9])[C:5]([NH:11]C(=O)C(F)(F)F)=[C:4]([N+:18]([O-:20])=[O:19])[CH:3]=1>C([O-])([O-])=O.[K+].[K+]>[F:1][C:2]1[CH:7]=[C:6]([N+:8]([O-:10])=[O:9])[C:5]([NH2:11])=[C:4]([N+:18]([O-:20])=[O:19])[CH:3]=1참가 물질
3
실험 절차
A solution of 4-fluoro-2,6-dinitro-(trifluoroacetamido)benzene (297 mg, 1.00 mmol) in 10% K2CO3 (10 mL) was refluxed for 1 h, then cooled to room temperature to give yellow crystals. It was filtered and washed with cold water (2 x 1 mL), affording 105 mg (52%) of the title compound. 1H NMR (DMSO-d6): δ 8.254 (s, 2H), 8.460 (d, 2H, J=8.4).
후처리
- customto give yellow crystals
- filtrationIt was filtered
- washwashed with cold water (2 x 1 mL)
출처 및 근거
- ORD 기록
- ord-7ea9f048dece4d2ebbd534367a8a0056
- 출처 데이터셋
- uspto-grants-1999_11
- 특허 번호
- US05977107
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