2-Naphthalenethiol → HCID 21830630, 화합물

HRID 1600893노트

반응식

HRID 1600893 반응식
[CH:1]1[CH:10]=[C:9]2[C:4]([CH:5]=[C:6]([SH:11])[CH:7]=[CH:8]2)=[CH:3][CH:2]=1.[N:12]1[CH:17]=[CH:16][CH:15]=[C:14]([CH2:18][CH2:19][C:20](=[O:23])[CH:21]=[CH2:22])[CH:13]=1>C(O)C>[N:12]1[CH:17]=[CH:16][CH:15]=[C:14]([CH2:18][CH2:19][C:20](=[O:23])[CH2:21][CH2:22][S:11][C:6]2[CH:7]=[CH:8][C:9]3[C:4](=[CH:3][CH:2]=[CH:1][CH:10]=3)[CH:5]=2)[CH:13]=1

참가 물질

4

반응물 2

HCID 70582-NaphthalenethiolHCID 218306261-(3-Pyridyl)-4-penten-3-one

생성물 1

HCID 21830630HCID 21830630, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

2-Thionaphthol was added to a solution of 1-(3-pyridyl)-4-penten-3-one (0.200 g) in ethanol (30 ml) followed by stirring overnight at room temperature. The ethanol was removed under reduced pressure and the residue purified by column chromatography over silica eluting with dichloromethane:ethyl acetate (2:1) to give the sub-title compound as a white solid (0.142 g).

후처리

  1. customThe ethanol was removed under reduced pressure
  2. customthe residue purified by column chromatography over silica eluting with dichloromethane:ethyl acetate (2:1)

출처 및 근거

ORD 기록
ord-59a8a781c3df46478763d2b69215da3e
출처 데이터셋
uspto-grants-1999_11
특허 번호
US05977105

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