참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Toluene | HCID 1140 | — |
| 반응물 | Allyl chloride | HCID 7850 | — |
| 반응물 | Dimethoxydimethylsilane | HCID 66187 | — |
| 반응물 | 1,1-Diethenyl-1,3,3,3-tetramethyldisiloxane | HCID 17760531 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | Silane, (3-chloropropyl)dimethoxymethyl- | HCID 87491 | 40% |
반응 단계
306 mg Of allyl chloride, 530 mol of dimethyldimethoxysilane, and 77 mg of toluene were placed in a glass reaction tube and 0.01 ml of acetic acid was added to this mixture. Then, 0.005 mol of a toluene solution of a 0-valent platinum complex of divinyltetramethyldisiloxane (platinum content: 0.4 wt %) was added to this mixture. The reaction tube was sealed and heated for 2 hours in an oil bath at 50° C. When the contents were analyzed by GC-MS following cooling, the conversion rate of allyl chloride was 100% and γ-chloropropylmethyldimethoxysilane was produced at a yield of 40%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05986124 |
|---|
| 출처 데이터셋 | uspto-grants-1999_11 |
|---|
| ORD ID | ord-b4e3bcf31e834ebf90cd98fd10fe859d |
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| 출처 메모 | uspto-grants-1999_11 |
|---|
