Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Perillaldehyde → Perilla alcohol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Perillaldehyde | HCID 16441 | — |
| 반응물 | Selenium Dioxide | HCID 24007 | — |
| 반응물 | (+)-Limonene | HCID 440917 | — |
| 촉매 | chromium (VI) trioxide | HCID 10219390 | — |
| 생성물 | Perilla alcohol | HCID 369312 | — |
반응 단계
Perillyl alcohol can be produced by reacting limonene with selenium dioxide (that is toxic) and other oxidants (that are difficult to work with i.e., anhydrous chromium trioxide) to yield various oxidation products, including a small amount of perillaldehyde. Once isolated, perillaldehyde is reduced to afford perillyl alcohol. While this two-step process is conceptually attractive, the oxidation of limonene to give perillyl alcohol proceeds in a low overall yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05994598 |
| 출처 데이터셋 | uspto-grants-1999_11 |
| ORD ID | ord-efc8b7b2544149a1a9a6fdf90618994b |
| 출처 메모 | uspto-grants-1999_11 |