Methanethiol → HCID 21519568, 화합물

반응식

[CH:1]12[C:7]([CH3:9])([CH3:8])[CH:6]1[C:5](=[O:10])[CH:4]=[C:3]([CH3:11])[CH2:2]2.[CH3:12][SH:13]>>[CH3:12][S:13][C:3]1([CH3:11])[CH2:4][C:5](=[O:10])[CH:6]2[C:7]([CH3:8])([CH3:9])[CH:1]2[CH2:2]1

참가 물질

반응물 2

HCID 878Methanethiol

HCID 135028754,7,7-Trimethylbicyclo[4.1.0]hept-3-en-2-one

생성물 1

HCID 21519568HCID 21519568, 화합물

실험 절차

In accordance with the procedure of Example 8 car-3-en-5-one is reacted with methylmercaptan by heating the reaction mixture in a suitable pressure-vessel for 3 hours to yield 3-methylthio-caran-5-on, boiling point ca 70° at 0.5 mm Hg, nD20 = 1.5224.

후처리

temperatureby heating the reaction mixture in a suitable pressure-vessel for 3 hours

출처 및 근거

ORD 기록: ord-41fc4db6e15947e59f0926f50c249b8f
출처 데이터셋: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03950429

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