4-Tert-octylphenol → 4-Tert-octylcatechol

HRID 1605629

반응식

HRID 1605629 반응식
CCC(OO)=[O:4].[C:7]([C:15]1[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][CH:16]=1)([CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:9])[CH3:8]>CC(C)=O>[C:7]([C:15]1[CH:20]=[C:19]([OH:4])[C:18](=[CH:17][CH:16]=1)[OH:21])([CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:8])[CH3:9]

참가 물질

4

반응물 2

HCID 88144-Tert-octylphenolHCID 65136Perpropionic acid

생성물 1

HCID 708284-Tert-octylcatechol수율 58%

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

The procedure of Example 9 was repeated, except 10.4g (0.1 mol) of perisobutyric acid in the form of about 20 weight% acetone solution was added over 30 minutes in place of perpropionic acid. Consequently, the conversion of para-tert.-octyl phenol was 13.2%, 4-tert.-octyl pyrocatechol was formed in a yield of 58% based on the converted octyl phenol and the conversion of perisobutyric acid was 100%.

출처 및 근거

ORD 기록
ord-68b802726e934ca9a2f2937935a17169
출처 데이터셋
uspto-grants-1976_04
특허 번호
US03950437

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