Water → HCID 22760978, 화합물

HRID 1605637노트

반응식

HRID 1605637 반응식
[O:1]=[C:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-].O>CCOCC>[OH:1][CH:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1

참가 물질

5

반응물 3

HCID 962WaterHCID 21226445Aluminium lithium hydrideHCID 22760937HCID 22760937, 화합물

생성물 1

HCID 22760978HCID 22760978, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

6.2 g of 2-keto-1,2,3,4-tetrahydro-tribenzo(b,d,f)-oxepine are added to a suspension of 3.7 g of lithiumaluminiumhydride in 300 ml of dry ether. After refluxing for 2 hours 14.8 ml of water are added carefully. The suspension obtained is filtered off and after that the filtrate is dried and evaporated to dryness.

후처리

  1. additionare added carefully
  2. customThe suspension obtained
  3. filtrationis filtered off
  4. customafter that the filtrate is dried
  5. customevaporated to dryness

출처 및 근거

ORD 기록
ord-40a252d0c60f46e7984a0e90e2e9ff6d
출처 데이터셋
uspto-grants-1976_04
특허 번호
US03950425

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