Sodium Azide → 4-Azidocarbonylphthalic anhydride

HRID 1605814

반응식

HRID 1605814 반응식
[N-:1]=[N+:2]=[N-:3].[Na+].Cl[C:6]([C:8]1[CH:9]=[C:10]2[C:15](=[O:16])[O:14][C:12](=[O:13])[C:11]2=[CH:17][CH:18]=1)=[O:7]>CC(C)=O>[N:1]([C:6]([C:8]1[CH:9]=[C:10]2[C:15](=[O:16])[O:14][C:12](=[O:13])[C:11]2=[CH:17][CH:18]=1)=[O:7])=[N+:2]=[N-:3]

참가 물질

4

반응물 2

HCID 33557Sodium AzideHCID 70998Trimellitic anhydride chloride

생성물 1

HCID 538062294-Azidocarbonylphthalic anhydride

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

A total of 3.25 g of sodium azide was added in portions to a solution of 10.5 g of 4-chlorocarbonylphthalic anhydride in 100 ml of acetone. The mixture was allowed to stand for 17 hours at room temperature (circa 25°C) after which the yellow solution so obtained was evaporated to dryness under reduced pressure. There was thus obtained a substantially quantitative yield of 4-azidocarbonylphthalic anhydride in the form of a crystalline solid having a melting point of 100° to 103°C with decomposition.

후처리

  1. custom(circa 25°C) after which the yellow solution so obtained
  2. customwas evaporated to dryness under reduced pressure

출처 및 근거

ORD 기록
ord-bba363dadea54fd6a64cca994e568a00
출처 데이터셋
uspto-grants-1976_04
특허 번호
US03951922

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