Hydrogen Peroxide → 3-Butylsulphinyl-1,2,4-triazole

HRID 1606060노트

반응식

HRID 1606060 반응식
[CH2:1]([S:5][C:6]1[N:10]=[CH:9][NH:8][N:7]=1)[CH2:2][CH2:3][CH3:4].[OH:11]O>C(O)(=O)C>[CH2:1]([S:5]([C:6]1[N:10]=[CH:9][NH:8][N:7]=1)=[O:11])[CH2:2][CH2:3][CH3:4]

참가 물질

4

반응물 2

HCID 784Hydrogen PeroxideHCID 178454955HCID 178454955, 화합물

생성물 1

HCID 1784555543-Butylsulphinyl-1,2,4-triazole

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

To a solution of 15.7 g. 3-butylthio-1,2,4-triazole in 60 ml. glacial acetic acid was added 100 vol. hydrogen peroxide solution (11.4 ml., 1 molecular proportion). The reaction mixture was cooled occasionally during 1 hour to maintain the reaction temperature at 25° - 30°C., and then kept at room temperature for 24 hours. The resulting solution was distilled under reduced pressure to produce a solid residue which was recrystallized from ethyl acetate to give 3-n-butylsulphinyl-1,2,4-triazole, m.p. 82° - 83°C.

후처리

  1. temperatureThe reaction mixture was cooled occasionally during 1 hour
  2. temperatureto maintain the reaction temperature at 25° - 30°C.
  3. distillationThe resulting solution was distilled under reduced pressure
  4. customto produce a solid residue which
  5. customwas recrystallized from ethyl acetate

출처 및 근거

ORD 기록
ord-42e4655e89124dc2b2481e0603c25349
출처 데이터셋
uspto-grants-1976_04
특허 번호
US03952001

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