Ethanol → HCID 901667, 화합물

HRID 1606770노트

반응식

HRID 1606770 반응식
[CH:1]1[C:9]2[C:8]3[CH:10]=[CH:11][CH:12]=[CH:13][C:7]=3[S:6][C:5]=2[C:4]([O:14][C:15]([CH3:20])([CH3:19])[C:16]([OH:18])=[O:17])=[CH:3][CH:2]=1.[CH2:21](O)[CH3:22]>>[CH:1]1[C:9]2[C:8]3[CH:10]=[CH:11][CH:12]=[CH:13][C:7]=3[S:6][C:5]=2[C:4]([O:14][C:15]([CH3:20])([CH3:19])[C:16]([O:18][CH2:21][CH3:22])=[O:17])=[CH:3][CH:2]=1

참가 물질

3

반응물 2

HCID 702EthanolHCID 901653HCID 901653, 화합물

생성물 1

HCID 901667HCID 901667, 화합물

실험 절차

2-(4-Dibenzothiophenoxy)-2-methylpropionic acid (9.5 g) was dissolved in 500 ml absolute ethanol. Dry hydrogen chloride was bubbled through for 3 hours, and the mixture was stored over night. After evaporation of the solvent, the residue was dissolved in 250 ml ether, washed with sodium bicarbonate solution, dried and evaporated to give 8.5 g of a brown liquid, b.p. 155-170/0.001 mm Hg.

후처리

  1. customDry hydrogen chloride was bubbled through for 3 hours
  2. waitthe mixture was stored over night
  3. customAfter evaporation of the solvent
  4. dissolutionthe residue was dissolved in 250 ml ether
  5. washwashed with sodium bicarbonate solution
  6. customdried
  7. customevaporated

출처 및 근거

ORD 기록
ord-9d99d390940b49229779ec2f5a20db19
출처 데이터셋
uspto-grants-1976_04
특허 번호
US03953601

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