Benzene → 1-Aminotetralin, (R)-

반응식

[C:1]([NH:9][C@H](C(O)=O)CCC(O)=O)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:19]1[CH:24]=CC=C[CH:20]=1>>[C@H:1]1([NH2:9])[C:2]2[C:3](=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH2:24][CH2:19][CH2:20]1

참가 물질

반응물 2

HCID 241Benzene

HCID 11345724N-Benzoyl-L-glutamic acid

생성물 1

HCID 70580721-Aminotetralin, (R)-

실험 절차

The (R) amine is made in the same way as described in Example 8, but from the salt from N-benzoyl-(S)-glutamic acid. It has [α]D25 -54.0° (c 5.1, benzene).

출처 및 근거

ORD 기록: ord-b2b3e593e34e4306ade838d036c22bcf
출처 데이터셋: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03953606

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