2-Methoxyethylamine → 5-Chloro-N1-(2-methoxyethyl)-N3-methyl-2-nitro-1,3-benzenediamine

HRID 1606856노트

반응식

HRID 1606856 반응식
[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([Cl:9])[CH:6]=[C:5](Cl)[C:4]=1[N+:11]([O-:13])=[O:12].[CH3:14][O:15][CH2:16][CH2:17][NH2:18]>>[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([Cl:9])[CH:6]=[C:5]([NH:18][CH2:17][CH2:16][O:15][CH3:14])[C:4]=1[N+:11]([O-:13])=[O:12]

참가 물질

3

반응물 2

HCID 80182-MethoxyethylamineHCID 20071071HCID 20071071, 화합물

생성물 1

HCID 198511585-Chloro-N1-(2-methoxyethyl)-N3-methyl-2-nitro-1,3-benzenediamine

실험 절차

0.09 mole (20 g of 2-methylamino-4,6-dichloro nitrobenzene was added portionwise to 80 ml of 2-methoxyethyl amine preheated to 80° C. After 2 hours' heating, the reaction medium was diluted with 100 ml of ice water and the desired product precipitated out. After filtering, water washing then vacuum drying in the presence of P2O5, it was recrystallized from 96° ethanol. It melted at 93° C.

후처리

  1. custompreheated to 80° C
  2. temperatureAfter 2 hours' heating
  3. customthe desired product precipitated out
  4. filtrationAfter filtering
  5. dry with materialwater washing then vacuum drying in the presence of P2O5, it
  6. customwas recrystallized from 96° ethanol

출처 및 근거

ORD 기록
ord-d3c264f613b54c85a60194c974e79929
출처 데이터셋
uspto-grants-1989_09
특허 번호
US04863482

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