Sodium Methoxide → HCID 19851157, 화합물

HRID 1606857노트

반응식

HRID 1606857 반응식
[CH3:1][NH:2][C:3]1[CH:8]=[C:7](Cl)[CH:6]=[C:5]([NH:10][CH2:11][CH2:12][O:13][CH3:14])[C:4]=1[N+:15]([O-:17])=[O:16].[CH3:18][O-:19].[Na+]>CO>[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([O:19][CH3:18])[CH:6]=[C:5]([NH:10][CH2:11][CH2:12][O:13][CH3:14])[C:4]=1[N+:15]([O-:17])=[O:16]

참가 물질

4

반응물 2

HCID 10942334Sodium MethoxideHCID 198511582-Methylamino-6-(beta-methoxyethyl)amino-4-chloronitrobenzene

생성물 1

HCID 19851157HCID 19851157, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

0.019 mole (5 g) of 2-methylamino-6-(β-methoxyethyl)amino-4-chloronitrobenzene was refluxed with 35 ml of 26% sodium methylate in methanol for 45 minutes then diluted with 100 ml of ice water to precipitate the desired product. Following filtering, water washing and drying under vacuum in the presence of P2O5, the product obtained was recrystallized from isopropanol. It melted at 84° C.

후처리

  1. customto precipitate the desired product
  2. filtrationFollowing filtering
  3. dry with materialwater washing and drying under vacuum in the presence of P2O5
  4. customthe product obtained
  5. customwas recrystallized from isopropanol

출처 및 근거

ORD 기록
ord-d58a90feab3246739159828477f4c590
출처 데이터셋
uspto-grants-1989_09
특허 번호
US04863482

반응 노트

불러오는 중…