Oxalyl chloride → HCID 22168546, 화합물

HRID 1607865노트

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HRID 1607865 반응식
[C:1]([CH2:4][C:5]1[CH:10]=[CH:9][C:8]([CH2:11][C:12]([O:14][CH3:15])=[O:13])=[CH:7][CH:6]=1)(O)=[O:2].C(Cl)(=O)C([Cl:19])=O>O1CCCC1>[C:12]([CH2:11][C:8]1[CH:9]=[CH:10][C:5]([CH2:4][C:1]([Cl:19])=[O:2])=[CH:6][CH:7]=1)([O:14][CH3:15])=[O:13]

참가 물질

4

반응물 2

HCID 65578Oxalyl chlorideHCID 14219918HCID 14219918, 화합물

생성물 1

HCID 22168546HCID 22168546, 화합물

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

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온도
45 °C

실험 절차

A 3.04 g portion of methyl 4-carboxymethylphenylacetate, prepared above, was dissolved in 50 mL of anhydrous tetrahydrofuran. After the addition of2.5 mL oxalyl chloride, the mixture was stirred for 4 hours. The solvents were evaporated under a stream of dry nitrogen as the flask was warmed to 45° C. Any remaining solvent or oxalyl chloride was then removed under high vacuum; the product was used without further purification.

후처리

  1. customThe solvents were evaporated under a stream of dry nitrogen as the flask
  2. customAny remaining solvent or oxalyl chloride was then removed under high vacuum
  3. customthe product was used without further purification

출처 및 근거

ORD 기록
ord-8a8e2af98bb542d2b303768ccd815052
출처 데이터셋
uspto-grants-1989_09
특허 번호
US04868132

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