Hydrogen Sulfide → HCID 19848484, 화합물
반응식
N1CCCCC1.[OH-].C([N+](C)(C)C)C1C=CC=CC=1.[CH:19]([N:21]([CH2:25][CH:26]=[CH2:27])[CH2:22][CH:23]=[CH2:24])=[O:20].[SH2:28]>CO>[CH:19]([N:21]1[CH2:25][CH:26]([CH3:27])[S:28][CH:23]([CH3:24])[CH2:22]1)=[O:20]참가 물질
6
실험 절차
Piperidine (10 ml) and 10 ml of a 40% solution of benzyltrimethylammoniumhydroxide in methanol were added to a solution of N-formyl-diallylamine (55 g) in methanol (200 ml). Hydrogen sulfide (50 g) was introduced into the resulting solution, and unreacted hydrogen sulfide was kept at reflux for 7 hours by means of "cold finger". The mixture was left at room temperature for 48 hours, flushed with nitrogen, diluted with ether, and washed with water. The organic phase was dried, and the solvent evaporated in vacuo. Distillation of the residue gave the title compound with boiling point 145° C./15 mmHg.
후처리
- temperatureat reflux for 7 hours by means of "cold finger"
- customflushed with nitrogen
- additiondiluted with ether
- washwashed with water
- customThe organic phase was dried
- customthe solvent evaporated in vacuo
- distillationDistillation of the residue
출처 및 근거
- ORD 기록
- ord-e0c489c0daac4c04bbda3865cc1b37aa
- 출처 데이터셋
- uspto-grants-1989_09
- 특허 번호
- US04870063
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