3,3-Dinitroazetidine → 3,3-Dinitroazetidinium 2,4-dinitroimidazolate

HRID 1608676노트

반응식

HRID 1608676 반응식
[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH:6][CH2:5]1)([O-:3])=[O:2].[N+:11]([C:14]1[NH:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12]>C(#N)C>[N+:11]([C:14]1[N-:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12].[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH2+:6][CH2:5]1)([O-:3])=[O:2]

참가 물질

4

반응물 2

HCID 52317063,3-DinitroazetidineHCID 178526857HCID 178526857, 화합물

생성물 1

HCID 1317189183,3-Dinitroazetidinium 2,4-dinitroimidazolate수율 95%

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

3,3-Dinitroazetidine free base (1.0 g) was added to a solution of 2,4-dinitroimidazole (1.07 g) in 50 ml of warm acetonitrile. The solution was allowed to cool and the majority of the solvent evaporated. The remaining slurry was filtered and dried to give 1.98 g of the resultant product, 3,3-dinitroazetidinium 2,4-dinitroimidazolate (95% yield).

후처리

  1. temperatureto cool
  2. customthe majority of the solvent evaporated
  3. filtrationThe remaining slurry was filtered
  4. customdried

출처 및 근거

ORD 기록
ord-f2cc1d08b8f14befacdfcb47b96c50ce
출처 데이터셋
uspto-grants-1995_03
특허 번호
US05395945

반응 노트

불러오는 중…