Bicyclo(2.2.1)heptan-2-one → 1,2,3,4-Tetrahydro-1,4-methanoacridin-9-amine

반응식

[C:1](#[N:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[NH2:4].[CH2:10]1[CH:14]2[CH2:15][C:16](=O)[CH:12]([CH2:13]2)[CH2:11]1>>[CH2:15]1[CH:14]2[C:10]3[C:11]([CH:12]([CH2:13]2)[CH2:16]1)=[N:4][C:3]1[C:2](=[CH:8][CH:7]=[CH:6][CH:5]=1)[C:1]=3[NH2:9]

참가 물질

반응물 2

HCID 10345Bicyclo(2.2.1)heptan-2-one

HCID 729132-Aminobenzonitrile

생성물 1

HCID 143728181,2,3,4-Tetrahydro-1,4-methanoacridin-9-amine

실험 절차

Anthranilonitrile (ortho-isomer) is allowed to react with norcamphor to obtain 9-amino- 1,4-methano- 1,2,3,4-tetrahydroacridine (Formula VIa). ##STR8##

출처 및 근거

ORD 기록: ord-c022a13c3cba4583a966362b0bd7240f
출처 데이터셋: uspto-grants-1995_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05401749

반응 노트

불러오는 중…