2-Methylpyridine-5-boronic acid → HCID 136167077, 화합물

반응식

Br[C:2]1[CH:7]=[CH:6][C:5]([CH:8]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH2:9]/[C:10](/[C:13]2[CH:18]=[CH:17][N:16]=[CH:15][CH:14]=2)=[N:11]\[OH:12])=[CH:4][CH:3]=1.[CH3:25][C:26]1[N:31]=[CH:30][C:29](B(O)O)=[CH:28][CH:27]=1>>[CH3:25][C:26]1[N:31]=[CH:30][C:29]([C:2]2[CH:7]=[CH:6][C:5]([CH:8]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[CH2:9]/[C:10](/[C:13]3[CH:18]=[CH:17][N:16]=[CH:15][CH:14]=3)=[N:11]\[OH:12])=[CH:4][CH:3]=2)=[CH:28][CH:27]=1

참가 물질

반응물 2

HCID 27630812-Methylpyridine-5-boronic acid

HCID 136167080HCID 136167080, 화합물

생성물 1

HCID 136167077HCID 136167077, 화합물

실험 절차

In analogy to example 22, from (E)-3-(4-bromo-phenyl)-3-phenyl-1-pyridin-4-yl-propan-1-one oxime (example 5) and 6-methylpyridine-3-boronic acid was prepared the title compound as a colorless oil, MS (ESI+): m/z=394.1 ([M+H]+).

출처 및 근거

ORD 기록: ord-71a859914ca747de8fe844d71a4ee9ed
출처 데이터셋: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08765730B2

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